Dream of energy-collecting windows is one step closer to reality
Researchers at the University of Minnesota and University of Milano-Bicocca are bringing the dream of windows that can efficiently collect solar energy one step closer to reality thanks to high tech silicon nanoparticles.
The researchers developed technology to embed the silicon nanoparticles into what they call efficient luminescent solar concentrators (LSCs). These LSCs are the key element of windows that can efficiently collect solar energy. When light shines through the surface, the useful frequencies of light are trapped inside and concentrated to the edges where small solar cells can be put in place to capture the energy.
The research is published today in Nature Photonics.
Windows that can collect solar energy, called photovoltaic windows, are the next frontier in renewable energy technologies, as they have the potential to largely increase the surface of buildings suitable for energy generation without impacting their aesthetics—a crucial aspect, especially in metropolitan areas. LSC-based photovoltaic windows do not require any bulky structure to be applied onto their surface and since the photovoltaic cells are hidden in the window frame, they blend invisibly into the built environment.
The idea of solar concentrators and solar cells integrated into building design has been around for decades, but this study included one key difference—silicon nanoparticles. Until recently, the best results had been achieved using relatively complex nanostructures based either on potentially toxic elements, such as cadmium or lead, or on rare substances like indium, which is already massively utilized for other technologies. Silicon is abundant in the environment and non-toxic. It also works more efficiently by absorbing light at different wavelengths than it emits. However, silicon in its conventional bulk form, does not emit light or luminesce.
“In our lab, we ‘trick’ nature by shirking the dimension of silicon crystals to a few nanometers, that is about one ten-thousandths of the diameter of human hair,” said University of Minnesota mechanical engineering professor Uwe Kortshagen, inventor of the process for creating silicon nanoparticles and one of the senior authors of the study. “At this size, silicon’s properties change and it becomes an efficient light emitter, with the important property not to re-absorb its own luminescence. This is the key feature that makes silicon nanoparticles ideally suited for LSC applications.”
Using the silicon nanoparticles opened up many new possibilities for the research team.
“Over the last few years, the LSC technology has experienced rapid acceleration, thanks also to pioneering studies conducted in Italy, but finding suitable materials for harvesting and concentrating solar light was still an open challenge,” said Sergio Brovelli, physics professor at the University of Milano-Bicocca, co-author of the study, and co-founder of the spin-off company Glass to Power that is industrializing LSCs for photovoltaic windows “Now, it is possible to replace these elements with silicon nanoparticles.”
Researchers say the optical features of silicon nanoparticles and their nearly perfect compatibility with the industrial process for producing the polymer LSCs create a clear path to creating efficient photovoltaic windows that can capture more than 5 percent of the sun’s energy at unprecedented low costs.
“This will make LSC-based photovoltaic windows a real technology for the building-integrated photovoltaic market without the potential limitations of other classes of nanoparticles based on relatively rare materials,” said Francesco Meinardi, physics professor at the University of Milano-Bicocca and one of the first authors of the paper.
